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16 Modeling Absorption and Emission Spectra (Assignment)

Janice Hester

Four-part infographic illustrating the relationship between the wavelength (color) of light absorbed by an electron, the change in energy level of the electron, and the absorption lines in a spectrum. The graphic includes: (1) a simple diagram of a hydrogen atom; (2) a graph showing the relationship between color absorbed and electron jumps; (3) an illustration of the hydrogen absorption spectrum; and (4) a graph of hydrogen’s absorption spectrum.
Model of the energy levels in a hydrogen atom; transitions corresponding to the four absorption lines in hydrogen’s visible spectrum are diagrammed. Image credit: NASA, ESA, Leah Hustak (STScI)

Energy levels are often modeled as either concentric circles (left-hand diagram in the figure above) or a series of horizontal lines or “steps” (upper right).  In the concentric-circle model, the further away an energy level is from the nucleus, the higher its energy is. Electrons must gain energy to move out energy levels (to higher energy levels) and they loose energy when they move in energy levels (to lower energy levels). Arrows indicate a transition, or a change in an electron’s energy level.  The four arrows in the figure above indicate that an electron is moving from energy level 2 out to higher energy levels (by absorbing a photon).

 

Four-part infographic illustrating the relationship between the change in energy level of an electron, the wavelength (color) of light emitted by the atom, and the emission lines in the spectrum. The graphic includes: (1) a simple diagram of a hydrogen atom; (2) a graphic showing the relationship between electron drops and color emitted; (3) an illustration of the hydrogen emission spectrum; and (4) a graph of hydrogen’s emission spectrum.
Diagram of light being emitted by a hydrogen atom. Image credit: NASA, ESA, Leah Hustak (STScI)

When an electron drops down to a lower energy level; a photon is emitted.  This is diagrammed by showing an arrow pointing inward from the original energy level to the new energy level.

Emission Spectrum of Hydrogen

Hydrogen Energy Levels

Diagram of the energy levels in a hydrogen atom

The diagram above represents the energy levels of a hydrogen atom with a single transition shown.  In the transition in the diagram, the electron is loosing energy as it drops from the second energy level to the first.

Absorption Spectrum of a Model Atom

 

Illustration of the three types of spectra: continuous, emission, and absorption
Illustration of the three types of spectra: continuous, emission, and absorption. Image credit: NASA, ESA, Leah Hustak (STScI)

An element’s absorption spectrum is formed when a continuous spectrum passes through a gas of the element.  The atoms absorb photons and an electron in the atom transitions to a higher energy level (energy is transferred from the photon to the electron in the atom).  The absorption lines in the spectrum correspond to the allowed changes in energy between the energy levels.

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Astronomy Extras and Interactives Copyright © by Janice Hester. All Rights Reserved.