3.2 How to Identify Minerals

Charlene Estrada

Identifying Minerals

Given the narrow criteria, you might think that Earth’s minerals are pretty rare. However, our planet (and the greater Universe) has found thousands of unique ways to combine elements into crystalline solids. There are over 5,600 minerals that have been discovered on Earth so far! We also think there are at least another thousand or more that have yet to be discovered by mineral scientists, called mineralogists.

If there are so many minerals on Earth, how does a scientist tell one apart from another? If you found the crystal cluster pictured below in a cave, how would you know whether it was gypsum and not quartz?

Image of a colorless cluster of crystals
Fig. 3.2.1. A cluster of colorless crystals, each with well-defined faces. What might this mineral be?

Physical Properties of Minerals

Minerals are categorized based on their chemical composition (see table below). Some minerals within the same compositional group will have similar physical characteristics such as color or shape. These properties are usually related to the type of elements within a mineral or how the atoms are bonded.

Group Name Chemical Composition Examples
Native Elements Single Elements Sulfur, Silver, Gold
Silicates SiO2 Family Quartz, Feldspars, Micas
Carbonates CO3 Family Calcite
Sulfates SO4 Family Gypsum
Oxides Oxygen Anion Hematite, Magnetite
Sulfides Sulfur Anion Pyrite, Galena
Halides Chloride or Fluoride Anion Halite, Fluorite

Mineralogists have identified some simple physical tests (described in the above video) to determine the identity of different minerals. These tests are ideal because prior to their use, scientists had to rely on complex (and expensive!) instruments such as X-ray Diffractometers. With these physical identification tests, most minerals can be identified in the field by scientists and nonscientists alike! The physical properties of minerals include:

Below, we will explore each of these tests in more detail. You will find that some tests will be more useful than others. Which tests will you find to be the most reliable when identifying an unknown mineral?

Color

Color is one of the first things we notice about minerals, and for good reason. Some minerals are bright with reds, greens, blues, and yellows. These colors are determined by the main elements in a mineral’s chemical formula. For example, copper (Cu), will cause azurite to be blue and malachite to be green.

Green Malachite and Blue Azurite
Fig. 3.2.2. Rock containing green malachite and blue azurite.

Sometimes, minerals have trace elements within their structure that cause them to take on unique colors. These trace elements are often metals such as chromium (Cr), manganese (Mn), or titanium (Ti), and because they are present in such limited amounts, they do not appear in the mineral’s chemical formula.

There are certain minerals that are reliably a specific color. Malachite is green. Azurite is blue. Sulfur is yellow. Knowing these patterns makes it easier to identify certain minerals. However, there are a lot of minerals that take on a wide variety of colors. Quartz is a good example – depending on the trace elements hiding within its structure, it can be clear, white, pink, gray, black, yellow, or brown!

The many different colors of quartz
Fig. 3.2.3. Quartz can be nearly any color as shown in these pebbles.

Streak

Both gray and red hematite leave a diagnostic reddish-brown streak.
Fig. 3.2.4. Both samples of hematite (Fe2O3, gray on the left, red on the right) leave a diagnostic red-brown streak on a porcelain streak plate.

Streak is the color of a mineral’s powder. Streak is a more reliable property than color because streak does not vary between two samples of a mineral, even when those samples are different colors (see above example). Minerals that are the same color may have a different colored streak. Many minerals, such as the quartz, do not have a streak.

To check streak, scrape the mineral across an unglazed porcelain plate. Yellow-gold pyrite has a blackish streak, another indicator that pyrite is not gold, which always has a golden-yellow streak.

Brassy yellow pyrite leaves a dark gray streak and pink rhodochrosite leaves a white streak.
Fig. 3.2.5. Some minerals leave a different streak color than their bulk mineral would indicate. Left: Pyrite, Right: Rhodochrosite.

Luster

Luster describes the reflection of light off a mineral’s surface. Mineralogists have specific terms to describe luster. One straightforward way to classify luster is based on whether the mineral is metallic or non-metallic. Minerals that are opaque and shiny, such as pyrite, have a metallic luster.

Minerals such as quartz have a non-metallic luster, but there are still a variety of ways to describe how the light reflects off the mineral. Let’s take a look below:

LUSTER TYPE EXAMPLE
Adamantine
Diamond with Adamantine Luster
Fig. 3.2.6. Polished diamond
Vitreous
Quartz demonstrating vitreous luster
Fig. 3.2.7. Vitreous quartz
Silky
Selenite Gypsum demonstrating silky luster
Fig. 3.2.8. Selenite with silky luster
Greasy
Greasy luster demonstrated by Graphite
Fig. 3.2.9 Greasy graphite
Waxy
Waxy luster shown by Mimetite
Fig. 3.2.10. Mimetite with waxy luster
Dull/ Earthy
Earthy, Dull luster as shown by Kaolinite
Fig. 3.2.11. Kaolinite with dull luster.
Metallic
Metallic luster as shown by pyrite
Fig. 3.2.12. Pyrite with metallic luster.

Habit

A mineral’s habit is the crystal shape or texture in a given specimen. It can refer to the expression of a crystal shape or the shape of multiple crystals aggregated or bunched together. Besides color, it is often the first thing you might notice about a mineral. Crystal shapes are usually determined by the arrangement of the atoms within the crystal structure. For instance, minerals with a cubic atomic structure will have a tendency to grow into cube-shapes.

The table below displays some common mineral habits.

HABIT TYPE DESCRIPTION EXAMPLE
Prismatic Column-like with visible crystal faces
Quartz with Prismatic Habit
Fig. 3.2.13. Quartz with prismatic habit.
Acicular Thin, needle-like or in clusters
Acicular Crystal Habit shown by Rutile
Fig. 3.2.14. Rutile acicular habit.
Micaceous Flat and flaky, peels apart into layers
Micaeous habit shown by muscovite
3.2.15. Micaceous muscovite habit.
Botryoidal[/pb_glossary] Bubbling or globular, circular crystals

[caption id="attachment_1966" align="aligncenter" width="300"]Botryoidal habit demonstrated with hemimorphite 3.2.16. Botryoidal habit in hemimorphite[/caption]

[pb_glossary id="1631"]Equant Boxy or round with roughly equal dimensions
Equant habit shown with rounded zircon crystals
3.2.17. Round zircons showing equant habit.
Bladed Elongated but flattened crystals or clusters
Bladed crystal habit shown in Diopside
3.2.18. Bladed crystal habit in diopside.
Massive Grainy, with no distinct crystals
Massive/Granular habit shown by cobaltite
Fig 3.2.19. Cobaltite demonstrating massive habit

Breakage

What does a mineral look like when it is broken? Cleavage and/or fracture describes the appearance of a mineral when a crystal is broken from an external force such as physical weathering or when you strike it with a hammer.

Cleavage is the tendency for crystals to break along planar surfaces that are parallel to atomic planes. It is common to observe:

CLEAVAGE TYPE EXAMPLE

Basal: 1 direction of cleavage

Muscovite demonstrating basal cleavage.
Fig. 3.2.20. Muscovite demonstrating basal cleavage.
2 directions of cleavage, perpendicular
Orthoclase feldspar demonstrating 2-directional cleavage at 90 angles from one another.
Fig. 3.2.21. Orthoclase feldspar demonstrating 2-directional cleavage at 90° angles from one another.
2 directions of cleavage, non-perpendicular
Albite feldspar demonstrating 2-directional cleavage planes at non-90 angles
Fig. 3.2.22. Albite feldspar demonstrating 2-directional cleavage planes at non-90° angles.
Cubic: 3 directions of cleavage, perpendicular
Halite demonstrating cubic cleavage
Fig. 3.2.23. Halite demonstrating cubic cleavage.
Rhombohedral: 3 directions of cleavage, rhombohedral
Calcite demonstrating rhombohedral cleavage.
Fig. 3.2.24. Calcite demonstrating rhombohedral cleavage.
Octahedral: 4 directions of cleavage (rare)
Fluorite demonstrating octahedral cleavage.
Fig. 3.2.25. Fluorite demonstrating octahedral cleavage.

Some minerals do not break along smooth planes at all! Such a tendency for a mineral to break unevenly is called fractureMetals usually fracture into jagged edges. Some minerals, such as quartz, form smooth curved surfaces when they fracture. This special type of breakage is called conchoidal fracture, and it is also seen in rocks such as obsidian and chert.

Conchoidal fracture demonstrated by quartz.
Fig. 3.2.26. Conchoidal fracture demonstrated by quartz.

Hardness

Mineral hardness is the mineral's resistance to being scratched. The hardness of the mineral can be defined by a numerical scale, called the Mohs Hardness Scale that goes from 0-10. You can test the hardness of a mineral using everyday objects like a penny, fingernail, nail, glass, or file to find out where on the hardness scale the mineral lies.

Mohs Hardness Scale of Minerals: From 1 (softest) to 10 (hardest), the order goes: talc, gypsum, fingernail (2.5), calcite, penny (3.5), fluorite, apatite, glass plate (5.5), feldspar, steel file (6.5), quartz, topaz, corundum, diamond.
Fig. 3.2.27. Mohs Hardness Scale of Minerals

If you can scratch the mineral with the object, then the object is harder than the mineral. If the mineral can scratch the object, then the mineral is harder than the object. You can also use other minerals to assign a hardness number to a mineral. In other words, we assign a hardness number to a mineral by making relative observations!

Unique Properties

Some minerals, whether it is by chemical composition or the arrangement of their atomic structure, have unique properties that make them much more easily identifiable. Some glow brightly under UV light, others are magnetic. Some fizz when dilute acid is dripped onto their surfaces, and some are extremely dangerous! There's a wide range of unusual and interesting things that minerals can do!

Magnetism

Certain iron-bearing minerals can are strongly or weakly magnetic. The most well-known of these is the mineral for which this property is named: Magnetite.

Magnetite, or lodestone, attracting iron filings
Fig. 3.2.28. Magnetite, or lodestone, attracting iron filings

Fluorescence

When specific minerals are exposed to high-energy ultraviolet light, the atoms within them are excited to a higher energy state. As those atoms relax back down to their default state, they'll emit light at a new wavelength, which can mean that we'll see beautiful and bright neon colors! This neat visual property is called fluorescence.

Minerals glowing bright, neon colors under UV light, or "fluorescing"
Fig. 3.2.29. Minerals glowing bright, neon colors under UV light, or "fluorescing"

Effervescence

Effervescence is a mineral's reaction to acid. Geologists can often identify certain minerals by dripping small amounts of dilute hydrochloric acid (HCl) on them. This is called the "acid test". We often see the strongest reaction from the mineral calcite.

[Video Description: Hydrochloric acid is dripped onto the white calcite mineral and it begins to loudly fizz, foam, and bubble. Some smoke also begins to rise from the mineral as a very tiny amount of it dissolves.]

The reaction in the above video occurs because the carbonate group in calcite (CaCO3) easily dissolves into carbon dioxide (CO2) gas, which you can see by the fizzing and bubbling at the surface. Sometimes, depending on the purity of the mineral, you might even see vapor or smoke rising from the fizzing mineral!

This test is extremely useful for geologists because only carbonate materials will strongly react to the acid. Geologists can also identify some sedimentary and metamorphic rocks that contain these very same minerals based on this test.

Optical Properties

Some minerals can be completely transparent, but even if we can view images through certain crystals, they can appear different or distorted! Calcite is well-known to "double" images if you look through clear, transparent samples of this crystal. This property is called "Double Refraction".

Doubling of images with transparent calcite, called double refraction
Fig. 3.2.30. Doubling of images with transparent calcite, called double refraction

Translucent ulexite can transmit an entire image when polished. This unique ability to transmit images has given ulexite the nickname "TV Stone".

Polished ulexite demonstrating image transmission
Fig. 3.2.31. Polished ulexite demonstrating image transmission
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