4 3.4 Mineral Groups
Most minerals are made up of a cation (a positively charged ion) or several cations, plus an anion (a negatively charged ion (e.g., S2−)) or an anion complex (e.g., SO42−). For example, in the mineral hematite (Fe2O3), the cation is Fe3+ (iron) and the anion is O2− (oxygen). The two Fe3+ ions have an overall charge of +6 and that balances the overall charge of −6 from the three O2− ions.
We group minerals into classes on the basis of their predominant anion or anion complex. These include oxides, sulfides, carbonates, silicates, and others. Silicates are by far the predominant group in terms of their abundance within the crust and mantle. (They will be discussed in the next section). Some examples of minerals from the different mineral groups are given in Table 3.4.
| [Skip Table] | |
| Group | Examples |
|---|---|
| Oxides | Hematite (iron oxide Fe2O3), corundum (aluminum oxide Al2O3), water ice (H2O) |
| Sulfides | Galena (lead sulfide PbS), pyrite (iron sulfide FeS2), chalcopyrite (copper-iron sulfide CuFeS2) |
| Sulfates | Gypsum (calcium sulfate CaSO4·H2O), barite (barium sulfate BaSO4) (Note that sulfates are different from sulfides. Sulfates have the SO4−2 ion while sulfides have the S−2 ion) |
| Halides | Fluorite (calcium flouride CaF2), halite (sodium chloride NaCl) (Halide minerals have halogen elements as their anion — the minerals in the second last column on the right side of the periodic table, including F, Cl, Br, etc. — see the periodic table in Appendix 1: List of Geologically Important Elements and the Periodic Table.) |
| Carbonates | Calcite (calcium carbonate CaCO3), dolomite (calcium-magnesium carbonate (Ca,Mg)CO3) |
| Phosphates | Apatite (Ca5(PO4)3(OH)), Turquoise (CuAl6(PO4)4(OH)8·5H2O) |
| Silicates | Quartz (SiO2), feldspar (sodium-aluminum silicate NaAlSi3O8), olivine (iron or magnesium silicate (Mg,Fe)2SiO4) (Note that in quartz the anion is oxygen, and while it could be argued, therefore, that quartz is an oxide, it is always classed with the silicates.) |
| Native minerals | Gold (Au), diamond (C), graphite (C), sulphur (S), copper (Cu) |
Oxide minerals have oxygen (O2−) as their anion, but they exclude those with oxygen complexes such as carbonate (CO32−), sulfate (SO42−), and silicate (SiO44−). The most important oxides are the iron oxides hematite and magnetite (Fe2O3 and Fe3O4, respectively). Both of these are common ores of iron. Corundum (Al2O3) is used as an abrasive, but can also be a gemstone in its ruby and sapphire varieties. If the oxygen is also combined with hydrogen to form the hydroxyl anion (OH−) the mineral is known as a hydroxide. Some important hydroxides are limonite and bauxite, which are ores of iron and aluminum respectively. Frozen water (H2O) is a mineral (an oxide), but liquid water is not because it doesn’t have a regular lattice.
Sulfides are minerals with the S−2 anion, and they include galena (PbS), sphalerite (ZnS), chalcopyrite (CuFeS2), and molybdenite (MoS2), which are the most important ores of lead, zinc, copper, and molybdenum respectively. Some other sulfide minerals are pyrite (FeS2), bornite (Cu5FeS4), stibnite (Sb2S3), and arsenopyrite (FeAsS).
Sulfates are minerals with the SO4−2 anion, and these include anhydrite (CaSO4) and its cousin gypsum (CaSO4.2H2O) and the sulfates of barium and strontium: barite (BaSO4) and celestite (SrSO4). In all of these minerals, the cation has a +2 charge, which balances the −2 charge on the sulfate ion.
The halides are so named because the anions include the halogen elements chlorine, fluorine, bromine, etc. Examples are halite (NaCl), cryolite (Na3AlF6), and fluorite (CaF2).
The carbonates include minerals in which the anion is the CO3−2 complex. The carbonate combines with +2 cations to form minerals such as calcite (CaCO3), magnesite (MgCO3), dolomite ((Ca,Mg)CO3)[1], and siderite (FeCO3). The copper minerals malachite and azurite are also carbonates.
In phosphate minerals, the anion is the PO4−3 complex. An important phosphate mineral is apatite (Ca5(PO4)3(OH)), which is what your teeth are made of. Note that it is called a phosphate, not a hydroxide, even though it has a hydroxyl ion.
The silicate minerals include the elements silicon and oxygen in varying proportions ranging from Si : O2 to Si : O4. These are discussed at length in Section 2.4.
Native minerals are single-element minerals, such as gold, copper, sulfur, and graphite.
***See 3.10 for Text and Media Attributions
- The notations of two (or more) elements enclosed in parentheses with a comma between them: (Ca,Mg), indicates that both can be present, in varying proportions, but that there is still only one of them for each anion present. ↵
A class of minerals with a chemical composition of a metallic element bound with oxygen.
Contains one or more metal combined with sulfur.
A mineral group composed of the sulfate (SO4--) anion.
A mineral group composed of the chloride (Cl-) or fluoride (F-) anion.
A mineral group composed of the carbonate (CO3--) anion.
A group of minerals containing PO4
A mineral class that is primarily composed or defined by silicon (Si) and oxygen (O).
Native element minerals are those elements that occur in nature in uncombined form with a distinct mineral structure
