10.1 Fossil Fuels – An Overview

Jeff Simpson

Learning Objectives – By the end of this chapter, you should be able to do the following.

  • Describe the similarities and differences in formation of the three fossil fuels.
  • Explain why fossil are called hydrocarbons.
  • Link the energy in a molecule of a fossil fuel to the energy from the sun.
  • Explain why fossil fuels have been our preferred energy source.

The term describes a group of energy sources that were formed from ancient plants and animals during the Carboniferous period approximately 362-286 million years ago. This was long before the appearance of the dinosaurs ~252 million years ago.

 

Video 10.1.1 – Fossil Fuels (1:01)

Important Points From this Video

  • Fossil fuels formed in the Carboniferous Period, 360-286 MY (million years ago). This can vary to as long ago as 541 MYA to – 65 MYA.
  • Three variables in creating a fossil fuel are time, temperature and starting organic matter.
  • Coal comes from ferns, plants and trees.
  • Oil comes from small organisms like and algae where conditions caused complex organic material to reform.
  • Methane () or “natural gas” starts the same as oil but undergoes more heat and pressure.
  • Fossil fuel are desirable as they have high energy density – a lot of energy in a small mass.
  • Fossil fuels are used for electricity & transportation.  (They also are used in industry for heat.)
  • The unequal distribution of fossil fuels leads to global conflict.
  • Many of the easy-to-obtain fossil fuel deposits have been extracted.

At that warm time in Earth’s history, unlike today’s world with high mountains and deep oceans, much of Earth’s warm surface was covered with swamps and shallow seas teeming with microscopic animals and plants. As those organisms died, they sank to the bottom of those swamps and oceans, and, over millions of years began to break down under layers of sand, clay, and other minerals, leaving behind mostly carbon and oxygen. Just as in your kitchen, nature starts with different ingredients (depending on the organic material present) and applies pressure, heat, and time. Depending on the ‘baking’ process, the starting products can be transformed into either , (oil), and/or methane ().

Methane or natural gas was formed by the same process as oil but was exposed to more heat and pressure, causing it to further decompose and turn into a gaseous form.

 

Video 10.1.2 – Formation of Fossil Fuels (2:26)

 

Graph of selected energy densities.
Fig 10.1.1 -Energy density in megajoules per kilogram (MJ/kg)

These resources have powered industrialization over history and continue to do so today.Fossil fuels have a variety of applications from electricity production to transport fuels. They can also be used to make a variety of common products from plastics to cosmetics to even some medicines.They are the world’s dominant energy source.

Fossil fuels can be an abundant and cheap or in some cases a scarce and expensive form of energy depending on geographic location. For this reason, geopolitical issues arise due to scarcity caused by the natural geographic allocation of these highly valuable resources. Fossil fuels are considered nonrenewable resources because they take millions of years to form which means that once they are used, the resources will not be replenished in a human lifetime.

The gradual depletion of the most accessible fossil fuel reserves have forced companies to develop technologies for extracting more challenging or unconventional reserves in many cases this means additional safety and environmental concerns as well as higher costs fossil fuels are also the largest emitters of carbon dioxide a greenhouse gas which causes climate change in addition their production causes both environmental and human health issues these concerns have triggered society to look at alternate sources of energy that are more environmentally sustainable and renewable.

Hydrocarbons

are extractable sources of stored energy created by ancient ecosystems. The natural resources that typically fall under this category are coal, oil (petroleum), and natural gas. Living organisms such as plants, phytoplankton, algae, and cyanobacteria captured sunlight energy via photosynthesis. We could refer to these resources as fossil solar energy since the energy of the sun in the past has been converted into chemical energy within a fossil fuel. Fossil fuels are molecular chains of hydrogen and carbon, thus the name Hydrocarbons. Of course, as the energy is used, the once stored carbon enters the atmosphere, causing consequences for our climate system. Fossil fuels account for much of the energy used in the world [1].

Transforming matter from living organisms into hydrocarbons (fossil fuels) is complex. You may have heard that petroleum formed from dinosaur bones, but that is inaccurate. Most oil formed during the dinosaur era, the , but T-Rex and the megafauna contributed little to it. The real energy heroes are the plants and marine algae that lived at that time. But why? How?

During much of the Mesozoic, the earth’s climate was tropical, warm, and without polar ice caps. It was Plankton’s paradise, with lots of room to live and plenty of sunshine to live by. The continents were in different positions, maximizing the ocean surface where the algae lived and changing the way the ocean currents flowed. In fact, there was not much movement at the bottom of the ocean during the Mesozoic! (Fig 10.3). Without mixing and vigorous circulation, the oxygen did not reach the ocean floor and vast areas of it were . These conditions facilitated the chemical reactions needed to form hydrocarbons. The low oxygen conditions also prevail in swamps, bogs, marshes which were common during this Paleozoic (the era before the Mesozoic). In fact, most of our coal resources were deposited during the geologic period Carboniferous (part of the Paleozoic era); Carboniferous means coal-bearing, indicating the widespread deposition and formation of coal.

 

Image of a globe. The central part is occupied by continental crust joined together, it has brown colors. To the left and right of the central mass the color blue shows the ocean.
Figure 10.1.2- During the Triassic, a period of the Mesozoic, the continents were together forming a giant mass. This configuration changed the way the oceanic currents traveled. Oxygen did not reach deep parts of the ocean floor.
Key Takeaways
  • Fossil fuels and biofuels are organic matter that formed from the sun’s energy millions of years ago.
  • Most of a fossil fuel is made of the element carbon.

Cooking Fossil Organic Matter in Earth’s Kitchen 

A plot with Depth in km to the left and temperature on the other axe showing 3 different colored areas. The areas correspond to the conditions needed to generate biogenic gass, oil and thermogenic gas
Figure 10.1.5 – Depth and temperature conditions determine if the organic matter will form oil, biogenic gas or thermogenic gas. Credits: Earle, S

 

 

How does Earth turn organic matter into hydrocarbons? First, plants and plankton die and fall to the bottom of the swamp or sea, respectively, where piles of sediments quickly bury them. They do not decompose. Decomposition needs oxygen and because their environments lack oxygen, the organic matter is not oxi dized (decomposed) but reduced. (Rapid burial is the key). The chemical energy within the organisms’ tissues is transferred to surrounding geologic material (sediments, minerals). Again, the key here is that organisms DO NOT decompose, instead they transform into something else under the right heat and pressure conditions. It actually takes a defined range of temperature and pressure conditions over defined amounts of time to produce hydrocarbons, “the oil generation window“! Heat and pressure applied after the burial of sediments also can transform the organic matter trapped in them into “higher quality” materials (brown coal to anthracite, oil to gas) and/or migration of mobile materials, such as gas.

 

An Abbreviated History of Fossil Fuels

Video 10.1.3 –  300 Years of Fossil Fuels (5:38)

 

Main Points from the Video
1. We need to learn to live without burning fossil fuels.
2. We need to adapt to the end of economic growth as we have known it.
3. We need  support 7,000,000+ people.
4. We have to deal with our legacy of environmental destruction.