9.3 Arizona: The Copper State

Carolina Londono Michel

Image of wire copper
Figure 9.3.1 Copper Electric wires  are used in phones, cars, computer devices, and buildings.

Arizona’s economy thrives on mining. Arizona’s largest copper deposits rank among the biggest in the world, making the state one of the top copper suppliers for the last 150 years. In 2020, Arizona ranked second for the value of non-fuel mineral production in the United States, it produced more than $7 billion worth of non-fuel mineral commodities (USGS, 2021). The principal non-fuel mineral commodities are cement (portland), copper, molybdenum, concentrates, sand and gravel (construction), and stone (crushed) (USGS, 2021). Arizona also produces gemstones. It is world famous for its turquoise, peridotite, and perlite.

 

A metal deposit is a body of rock in which one or more metals have been concentrated to the point of being economically viable for recovery [3]. Some levels of important metals in average rocks are shown in Table 4, along with the typical grades, or concentrations, necessary to make a viable deposit and the corresponding concentration factors. For example, if we look at copper we can see that while average rock has around 40 ppm (parts per million) of copper, a grade of around 10,000 ppm or 1% is necessary to make a viable copper deposit. In other words, A copper ore rock has about 250 times as much copper as a typical rock. For the other elements in the list, the concentration factors are much higher. For gold, it’s 2,000 times and for silver, it’s around 10,000 times.

Some very significant concentration must take place to form a mineable deposit. This concentration may occur during the formation of the host rock, or after the rock forms, through a number of geologic processes. There is a very wide variety of ore-forming processes, and there are hundreds of types of mineral deposits. The origins of a few of them are described below.

Table 9.3.1. Typical Background levels of important metals
Metal Typical Background Level Typical Economic Grade* Concentration Factor
Copper 40 ppm 10,000 ppm (1%) 250 times
Gold 0.003 ppm 6 ppm (0.006%) 2,000 times
Lead 10 ppm 50,000 ppm (5% 5,000 times
Molybdenum 1 ppm 1,000 ppm (0.1%) 1,000 times
Nickel 25 ppm 20,000 ppm (2%) 800 times
Silver 0.1 ppm 1,000 ppm (0.1%) 10,000 times
Uranium 2 ppm 10,000 ppm (1%) 5,000 times
Zinc 50 ppm 50,000 ppm (5%) 1,000 times
It is important to note that the economic viability of any deposit depends on a wide range of factors including its grade, size, shape, depth below the surface, proximity to infrastructure, the current price of the metal, the labor and environmental regulations in the area, and many other factors. Source: [3]

 

Native Americans Contributions to Mining

Native Americans accrued and passed empirical knowledge by direct interaction with the natural world. This body of

Image showing a young woman graduating from school in her traditional Navajo clothes
Figure 9.3.2. Kiara Reed, a young Diné graduate, wears her traditional attire and turquoise and silver jewelry, along with graduation regalia. Photo courtesy of J. Johnson.

knowledge is variously referred to as Native science, ethnoscience, and Traditional Ecological Knowledge, TEK. TEK is practical, sophisticated, and can share the purposes and benefits of mainstream geology and ecology.

Indigenous peoples have expertise with diverse minerals. They hold specialized knowledge about mineral properties, qualities, and their occurrences on the land. For the Diné, a Tribal Nation of the Southwest, turquoise has cultural, religious, social, and economic relevance. The Diné (Navajo) word for turquoise is dotl’ izhi. The Navajo have long known where to find turquoise, how to extract it, and how to work with it to produce a myriad of objects. Navajo jewelry is famous around the globe for its beauty and high quality.

Quarrying, surface mining, and metallurgical knowledge have been present throughout the Americas for millennia. Native people applied TEK to manage and use lands and technologies that make their lives better (Cajete,2010). Further, Native miners and metalworkers improved imported European technology. They invented ore-crushing and automated coin-minting machines previously unknown in Europe. The metallurgical knowledge of South American tribes raised the efficiency of silver extraction and was apt for high altitudes, where it originated. These contributions to mining technology boosted the development of the modern industrial era (Cajete, 2010).

 

 

Metalogenesis. The Origin of Metal Deposits.

Volcanogenic Massive Sulfides VMS

Certain volcanic processes concentrate minerals, and the resulting deposits are called volcanogenic deposits. The word is composed of volcano and genesis = origin, which means that the deposits are originated by volcanic systems. Geochemists dubbed a particular kind of these mineral deposits “Volcanogenic Massive Sulfides (VMS)” given the unusually abundant mass of minerals.

Copper in Jerome, central Arizona, was mined from VMS deposits associated with ancient submarine volcanoes. Briefly, 1,750 to 1,650 million years ago (Ma), in the Precambrian, the SW part of the United States did not exist. Instead of continental land, Arizona was under the ocean. The oceanic floor was active, with volcanoes and associated underwater hot springs that spewed hot liquids loaded with metals. Beneath the volcanoes and hot springs, laid a heat source (magmatic heat source in Fig 9.15). Ocean water can circulate through cracks and fractures within oceanic rocks, that is, groundwater flows under the ocean floor too! The groundwater that penetrates the oceanic rocks travels down, absorbing heat from the magmatic source. The deeper the water travels, the hotter it gets and at some point, it rises back up (see figure 9.15). You may remember a lava lamp and how the heat makes the blobs move when they get hot; like the blobs, the cold water from the ocean percolates down and rises as it collects heat.

The super-heated groundwater mobilizes the metals out of the volcanic rock, in a process called leaching. The sulfide minerals (including pyrite (FeS2), sphalerite (ZnS), chalcopyrite (CuFeS2), and galena (PbS)), are generally present in very high concentrations in the oceanic rocks around the volcanic system. Recall that water is a universal solvent. Its special properties allow water to remove and carry metals from the host rocks to other places. The super-heated water temperatures (250° to 300°C or 482-570 F!) increase the leaching capacity. When the hot, metal-loaded groundwater rises, it sips out through springs. But it encounters cold ocean water and the extreme temperature drop causes metallic minerals precipitation around the vents. The minerals that precipitate contain copper, lead, zinc, silver, and gold. The setting is comparable to what we know today as “black smokers”; submarine hot springs that occur near tectonic spreading centers (Ch 2.)

The mineral deposits at Jerome formed in submarine volcanic settings. You may wonder, if that is true, then why are those deposits now on land in Arizona? The answer is plate tectonics. In short, tectonic forces created what is now the southwest part of the US, and some of that ancient oceanic floor got pushed into the continent.

 

Figure 9.3.3. Left: A black smoker on the Juan de Fuca Ridge off the west coast of Northern United States. Right: A model of the formation of a volcanogenic massive sulfide deposit on the seafloor. 

 

Video 9.3.1. shows volcanic hydrothermal vents in the Caribbean. As the super hot fluid mixes with cold water, metal-rich minerals precipitate forming chimney-like structures and concentrating metal deposits. Gold and zinc and a host of metals are concentrated in this way. Black smokers are important for a variety of organisms that thrive around them. However, the conditions are so extreme that they are rightfully named ‘extremophiles’ or extreme lovers (4:56)

Porphyry Copper Deposits

deposits are the most important source of copper in British Columbia, the western United States, and Central and South America. Figure 9.3.6 shows a sketch of a porphyry copper deposit. Most porphyry deposits also host some gold, and in rare cases, gold is the primary commodity. Arizona examples include several large deposits that occur on a northwest-trending belt, in Fig 9.3.7.

Figure 9.3.4. A model for the formation of a porphyry deposit around an upper-crustal porphyritic stock and associated vein deposits [3].

 

This type of deposit is associated with rocks (Ch. 4), such as granite. An intrusion is a body of magma that ascends through the rock layer. As it rises, it loses heat and crystalizes into an intrusive, igneous rock. In Fig. 9.3.4, the intrusive igneous rock is the tongue-shaped feature protruding from the bottom; you can see the label porphyry intrusion to the right. A porphyry describes a rock texture in which individual mineral grains about a tenth to a half-inch in size are surrounded by smaller grains that are barely visible to the naked eye. The metallic mineral deposit forms around the cooling rock body, or , in the upper part of the crust. In figure 9.3.4., the porphyritic rock is cooling off, expelling magmatic water and interacting with the surrounding rocks. Similar to VMS, the convection of groundwater heated by the stock results in metal enrichment. A second source of water is the cooling magma, which is loaded with metals (Figure 9.3.3, right). The rocks in this type of deposit are normally highly fractured and brecciated, which facilitates the extraction. The important ore minerals include chalcopyrite (CuFeS2), bornite (Cu5FeS4), and pyrite in copper porphyry deposits, or molybdenite (MoS2) and pyrite in molybdenum porphyry deposits. Gold is present as minute flakes of native gold [3].

Arizona’s porphyry copper deposits date back to 70 million years ago. Intrusive activity and groundwater concentrated the copper and other metals below the ground. But, our dynamic planet shifts things around, and thanks to tectonic forces, weathering, and erosion, the rich metal deposits reached the surface millions of years later. Further, the geochemical processes that act during weathering enhance the copper concentration, a process called “secondary enrichment”.

Figure 9.3.5. Map of Arizona showing the location of the most common types of copper deposits. We generated the image using interactive the Mineral Resources Online Spatial Data, U.S. Geological Survey.

 

Secondary Enrichment

Secondary enrichment is a process that acts after the first enrichment we have already discussed. The secondary enrichment further concentrates metals by weathering processes. Rain precipitation on mineral deposits alters their composition, as you may recall from the weathering and mass wasting chapter. Precipitation can infiltrate and fill in spaces within rocks to become groundwater. In this movement, water can mobilize elements from a host rock and transport them downward, leaching the rock and concentrating elements of interest underground. When the percolating solution reaches the water table, the chemical conditions change and the transported elements precipitate. This leads to an enriched zone below the water table. Copper deposits may have to be enriched in this way to become ore.

Four profiles showing the continuous concentration of elements due to continuous rainfall, erosion of the top layer, more rainfall, further erosion and concentration of metals in rock
Figure 9.3.6. Rainfall and water that infiltrate moves the elements downward in the soil and rock column. Erosion removes the top. The process repeats until economic concentrations of metals are reached in this way.